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Combustion, Explosion and Shock Waves

2018 year, number 3

Influence of Activated Coal on the Thermal Decomposition of Hydroxylammonium Nitrate

M. K. Atamanov1,2, R. Amrouse3, K. Hori3, B. Ya. Kolesnikov2, Z.A. Mansurov1,2
1Al-Farabi Kazakh National University, Almaty, 480078 Kazakhstan
2Institute of Combustion Problems, Almaty, 480012 Kazakhstan
3Japan Aerospace Exploration Agency, Sagamihara, 2525210 Kanagawa, Japan
Keywords: нитрат гидроксиламмония, активированный уголь, скорость горения, дифференциальный термический анализ, масс-спектральный анализ, hydroxylammonium nitrate, activated carbon, burning rate, differential thermal analysis, mass spectral analysis

Abstract

This paper presents experimental results for the thermal decomposition of hydroxylammonium nitrate (HAN) in the presence of activated carbon with a high specific surface (up to 3000 m2/g) obtained by activation of rice husk with potassium hydroxide at a temperature of 700oC in the rotating spherical furnace. With addition of activated carbon, the temperature of the beginning of the decomposition of HAN reduced from 185 to 86±0.5oC. The burning rate of HAN doped with activated carbon increases to 400 mm/s at an overpressure of 6 MPa. It has been shown that the addition of activated carbon reduce the amount of NO x gases produced by decomposition to 30%.