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Avtometriya

2018 year, number 4

DIPOLE-DIPOLE INTERACTION IN A HELICAL MOLECULAR AGGREGAT

A. A. Zabolotskii
Institute of Automation and Electrometry, Siberian Branch, Russian Academy of Sciences, prosp. Akademika Koptyuga 1, Novosibirsk, 630090, Russia
Keywords: наноматериалы, спиральные структуры, экситоны, солитоны, nanomaterials, helical structures, excitons, solitons

Abstract

The formation and dynamics of excitations in an atomic or molecular nano chain of a helical shape is studied. The dipole-dipole interaction of the circular polarizations of optical transitions of neighboring molecules is taken into account. The derived Bloch equations are solved in a continuum approximation using the Frenet - Serret coordinate system. Solutions that describe the formation of stable localized structures, solitons, due to the curvature of the chain, which can have a critical influence on the luminescent properties of the chiral medium.