STRUCTURE OF ADDUCTS OF THE INTERMOLECULAR INTERACTION OF DIMETHYLPYRAZOLE AND DIPHENYLFORMAMIDINE WITH HYDROGEN HALIDES IN THE SOLUTION
S. F. Bureiko, S. Y. Kucherov
Keywords: structure of molecular and ionic complexes, hydrogen bond, proton transfer, solutions, IR spectroscopy, quantum chemical calculations
Pages: 285-291
Abstract
The structure of adducts forming in the solution due to the interaction of bifunctional azo compounds (dimethylpyrazole (DMP) and diphenylformamidine (DPFA)) with hydrogen halides (HF, HCl, and HBr) is found from the data of the IR absorption spectra and quantum chemical calculations. It is shown that in the interaction with HCl or HBr proton donors, proton transfer via the hydrogen bond to the basic N atom of the azo compound occurs with the formation of an NH+…Hal- ionic pair. Strong evidences of proton transfer and the anion-cation pair formation are not found for the DMP-НF structure, and complexes with the molecular N…HF hydrogen bond are the dominant structures. Geometric parameters of the formed structures are calculated. The formation of trimers, containing two molecules of the azo compound and one HHal molecule, with an increase in the nitrogenous base concentration is experimentally proved, and the trimer structure is determined.
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