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Journal of Structural Chemistry

2012 year, number 2

TEMPERATURE INDEPENDENCE OF SOLVATION NUMBERS OF ELECTROLYTES DETERMINED BY THE ADIABATIC COMPRESSION TECHNIQUE UP TO THE COMPLETE SOLVATION LIMIT

A. N. Ustinov, V. N. Afanasiev
Keywords: isothermal compressibility, adiabatic compressibility, compressibility of hydrated complexes, solvation numbers
Pages: 314-323

Abstract

The theory of the dependence of solvation numbers on the temperature is very popular today. However, according to our works, solvation numbers do not depend on temperature until the complete solvation limit is reached. The purpose of this paper is to address this apparent contradiction