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Atmospheric and Oceanic Optics

2018 year, number 6

1.
Aerosol optical characteristics retrieved from measurements of CIMEL sun photometer (AERONET) near Saint Petersburg

K.A. Volkova1, A.V. Poberovsky1, Yu.M. Timofeev1, D.V. Ionov1, B.N. Holben2, A. Smirnov2, I. Slutsker2
1Saint Petersburg State University, 1, Ulyanovskaya str., Petrodvorets, St. Petersburg, 198504, Russia
2NASA/Goddard Space Flight Center, Greenbelt, MD 20771, USA
Keywords: аэрозольная оптическая толщина, солнечный фотометр, параметр Ангстрема, aerosol optical depth, sun photometer, Angstrom exponent

Abstract >>
The measurements of CIMEL CE 318 sun photometer near Saint Petersburg within the International monitoring AERONET network are analysed. Typical regional aerosol optical characteristics (aerosol optical depth, Angstrom exponent, and single scattered albedo) and their variations are determined. Some regularities in variations in the aerosol parameters over the North-West region of the Russian Federation are revealed. The study is supplemented by the joint analysis of data from the nearby AERONET observation sites in Finland and Estonia, satellite measurements, and MERRA reanalysis data.



2.
Interannual variability of surface and integral moisture content in the European territory and atmospheric circulation

O.G. Khutorova, V.E. Khuturov, G.M. Teptin
Kazan Federal University, 18 Kremlyovskaya St., Kazan, 420008, Republic of Tatarstan, Russian Federation
Keywords: интегральное влагосодержание атмосферы, парциальное давление водяного пара, межгодовые процессы, дистанционное зондирование сигналами спутниковых навигационных систем, atmospheric integral moisture content, water vapor partial pressure, interannual processes, remote sensing by satellite navigation systems

Abstract >>
The variability of time series of the integral moisture content of the atmosphere and the surface partial pressure of water vapor for the territory of Europe over a long period have been studied. The main contribution to variance of moisture contents is given by seasonal variations; it is 60-70%. Mesoscale processes give 7-17%; synoptic processes give 17-27%. The linear trend contributes less than 1% to the overall variance of the variability of the atmospheric moisture content in Europe. It is shown that the interannual variability of the atmospheric moisture content is manifested both in the quasiperiodic variability of the annual mean values and in the variations in the intensity of the synoptic processes. The irregular coherence of variations in the circulation indices and surface partial pressure of water vapor in Europe with periods of 2-3 years, 5-6, 8-11, and 10-13 years is established.



3.
A numerical research of processes of transfer and transformation of gas and aerosol impurities in plumes of emissions of the Norilsk industrial region

V.F. Raputa1, D.V. Simonenkov2, B.D. Belan2, T.V. Yaroslavtseva3
1Institute of Computational Mathematics and Mathematical Geophysics of the Siberian Branch of the RAS, 6, Ac. Lavrentieva ave., 630090, Novosibirsk, Russia
2V.E. Zuev Institute of Atmospheric Optics of Siberian Branch of the Russian Academy of Science, 1, Academician Zuev square, Tomsk, 634021, Russia
3Novosibirsk Scientific Research Institute of Hygiene of the Federal Service for Supervision of Consumer Rights Protection and Human Welfare, 7, Parkhomenko Str., Novosibirsk, 630108, Russia
Keywords: атмосфера, загрязнение, модель, параметр, оценка, трансформация примеси, atmosphere, pollution, model, parameter, assessment, impurity transformation

Abstract >>
Models of estimation of average and maximum concentrations of chemically active impurities in cross sections of plumes from remote stationary sources are suggested. Approbation of the models is carried out on data of aircraft sounding of multicomponent pollution of the winter atmosphere of the Norilsk industrial region. Process of active transition gas ® particle, observed at a distance of 58-103 km from a source of emissions, is numerically studied. Average and maximum sulfur oxidation rates in the winter polar atmosphere are estimated as 0.027-0.034 h-1 and 0.055-0.07 h-1, respectively.



4.
The main precipitation modes over Mongolia and southern part of Eastern Siberia in July

O.Yu. Antokhina1, P.N. Antokhin1, E.V. Devyatova2, Yu.V. Martynova3,4, V.I. Mordvinov2,5
1V.E. Zuev Institute of Atmospheric Optics of Siberian Branch of the Russian Academy of Science, 1, Academician Zuev square, Tomsk, 634021, Russia
2Institute of Solar-Terrestrial Physics of the Siberian Branch of the RAS, 664033, Irkutsk, 126a, Lermontova street
3Institute of Monitoring of Climatic and Ecological Systems of the Siberian Branch of the Russian Academy of Sciences, 634055, Tomsk, 10/3, Academichesky ave
4Siberian Regional Hydrometeorological Research Institute, Novosibirsk, Russia, Russia, 630099, Novosibirsk, Sovetskaya, 30
5Irkutsk State University, 664003, Irkutsk, 1, Karl Marx Str
Keywords: атмосферные осадки, дипольные моды, оз. Байкал, р. Селенга, естественные ортогональные функции, precipitation, seesaw modes, Lake Baikal, the Selenga River, empirical orthogonal functions

Abstract >>
We investigated the main precipitation modes over Mongolia and southern part of Eastern Siberia in midsummer. We used precipitation data from GPCC archive (1979-2013). The EOF analysis was applied to the interannual change in July precipitation for two areas: “big” (90-120°E; 35-70°N) and “small” (the Selenga basin, 96-110°E; 46-54°N). The total amount of precipitation within the Selenga basin in July was calculated. According to the obtained estimates two leading EOFs (EOF1 + EOF2) explains 32.3 and 48.9% of the total variance for the big and small areas, respectively.



5.
The comparative analysis of electrical quantities of a surface layer during passage of cumulonimbus clouds in the warm and cold seasons

K.N. Pustovalov, P.M. Nagorskiy
Institute of Monitoring of Climatic and Ecological Systems of the Siberian Branch of the Russian Academy of Sciences, 634055, Tomsk, 10/3, Academichesky ave
Keywords: атмосферное электричество, кучево-дождевые облака, ливневые осадки, приземный слой атмосферы, atmospheric electricity, cumulonimbus, showers, surface air layer

Abstract >>
Using the monitoring data of electrical quantities of a surface layer in Tomsk in 2006-2017, the their slow variations connected with passage of cumulonimbus ( Cb ) clouds and concomitant weather phenomena in the warm and cold seasons were studied. In total, 453 and 210 events for warm and cold seasons, respectively, were considered. A statistical analysis of these slow variations in the electric field potential gradient was carried out. The distribution of the total duration of the potential gradient slow variations is described by the power-series distribution (Pareto distribution).



6.
Numerical study of direct variational data assimilation algorithm in the urban scenario

A.V. Penenko1, Z.S. Mukatova1, V.V. Penenko1, A.V. Gochakov2, P.N. Antokhin3
1Institute of Computational Mathematics and Mathematical Geophysics of the Siberian Branch of the RAS, 6, Ac. Lavrentieva ave., 630090, Novosibirsk, Russia
2Siberian Regional Hydrometeorological Research Institute, Russia, 630099, Novosibirsk, Sovetskaya, 30
3V.E. Zuev Institute of Atmospheric Optics of Siberian Branch of the Russian Academy of Science, 1, Academician Zuev square, Tomsk, 634021, Russia
Keywords: усвоение данных, вариационный подход, схема расщепления, В«Умный городВ», data assimilation, variational approach, splitting scheme, “smart city

Abstract >>
The performance of a direct variational data assimilation algorithm with quasi-independent data assimilation at individual steps of the splitting scheme was evaluated in the realistic scenario of the air pollution assessment in the city of Novosibirsk. An algorithm with minimization of the spatial derivative of the uncertainty (control) function, which is adjusted to assimilate data, was considered in the case of sparse monitoring network. The use of the spatial derivative minimization allowed increasing smoothness of the uncertainty (control functions) reconstructed, which has a positive effect on the reconstruction quality in the scenario considered.



7.
Numerical simulation of the hydraulic regime of the Lena River delta

A.I. Krylova, E.A. Antipova
Institute of Computational Mathematics and Mathematical Geophysics of the Siberian Branch of the RAS, 6, Ac. Lavrentieva ave., 630090, Novosibirsk, Russia
Keywords: неустановившееся движение воды, уравнения Сен-Венана, дельта р. Лены, основные протоки, расход воды, уровень свободной поверхности, неявная разностная схема, unsteady flaw motion, Saint-Venant equations, Lena River delta, main branch, water discharge, free surface level, implicit difference scheme

Abstract >>
The work is devoted to numerical simulation of the hydraulic regime of the Lena River delta based on the system of Saint-Venant equations. This system describes the unsteady motion of the river flow in one-dimensional approximation. The numerical solution of Saint-Venant differential equations is based on the use of an absolutely stable implicit difference scheme and a specially developed method of Gaussian elimination for a “tree” graph of branched and looped sections of the river network. The calculated water discharge distribution over the main branches of Lena River delta and the comparison between modeling runoff at the Olenekskaya hydrometric cross sections with the field data in 2005 are presented.



8.
Hydrochemical studies of water bodies in the area of oil-producing complexes

L.I. Svarovskaya, L.K. Altunina, I.G. Yashchenko
Institute of Petroleum Chemistry of the Siberian Branch of the RAS, 3, Academichesky ave., Tomsk, 634021, Russia
Keywords: гидрохимические исследования, водосборный бассейн рек, загрязнение нефтепродуктами, ароматические углеводороды нефти, картографирование, ГИС-технологии, hydrochemical studies, river watershed, oil pollution, oil aromatic hydrocarbons, mapping, GIS technologies

Abstract >>
Hydrochemical studies were carried out on the territory of oil-production enterprises of the Tomsk region located in the floodplain of the Ob and Vasyugan rivers. It was found out that oil products whose concentration exceeds the MPC value by 3-5 times are rated as the largest contributors to the pollution of rivers flowing through the territories of oil fields. The contents of chlorides, sulfates, calcium, salts of heavy metals, and magnesium exceeds the maximum permissible levels by several tens of times. The most dangerous for human health aromatic compounds were identified among oil pollutants, including pyrenes, fluoranthenes, chrysenes, benzanthracenes, which constitute a group of carcinogens. The main impact on water quality is exerted by surface runoff from the oil-polluted territory of the river watershed. For the spring period of 2014 the volume of oil products removed to the network of the Ob river was 3.2 tons on the territory of the Sovetskoye oil field, while the annual runoff was 4.9 tons. Geochemical data could be successfully used for mapping oil spill using GIS technologies and planning preventive measures for localization and restoration of contaminated sites in areas of oil and gas producing complexes.



9.
Modified beam-splitting 1 algoritm for solving the problem of light scattering on concave atmospheric ice crystals

D.N. Timofeev1, A.V. Konoshonkin1,2, N.V. Kustova1
1V.E. Zuev Institute of Atmospheric Optics of Siberian Branch of the Russian Academy of Science, 1, Academician Zuev square, Tomsk, 634021, Russia
2National Research Tomsk State University, 36, Lenin Avenue, Tomsk, 634050, Russia
Keywords: алгоритм, невыпуклые частицы, агрегаты, физическая оптика, геометрическая оптика, перистые облака, algorithm, concave particles, aggregates, physical optics, geometrical optics, cirrus clouds

Abstract >>
A modified beam-splitting algorithm for solving the problem of light scattering on atmospheric concave ice crystals being typical for cirrus clouds is developed. It is based on the beam-splitting algorithm for convex crystals that was created at Institute of Atmospheric Optics SB RAS. The algorithm is used for the solution of the light scattering problem for hollow-column particles and hexagonal column aggregates. The algorithm is on open access with open source code.



10.
Composition and properties of the surface of aerosol microparticles produced from nonporosity zinc oxide in ambient air

V.S. Zakharenko1, E.B. Daybova2
1Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia, Russia, 630090, Novosibirsk, Pr. akademika Lavrentieva, 5
2Siberian Research Institute of Agriculture and Peat, Gagarina Str., 3,Tomsk, 634050, Russia
Keywords: осажденный аэрозоль, плазмотронный ZnO, состав поверхности, фотодесорбция, фотоадсорбция NO, квантовый выход, поверхностное поглощение, precipitated aerosol, plasmotronic ZnO, surface composition, photodesorption, NO photoadsorption, quantum yield, surface absorption

Abstract >>
The adsorption and photosorption properties of plasmatronic ZnO particles under ambient air are investigated. The composition analysis of surface layer adsorbed on microparticles is carried out. The kinetics of desorption and adsorption processes on microparticle surfaces under darkness and illumination are studied. The quantum yield and spectral dependency of quantum yield of NO photoadsorption are determined.



11.
Four-channel photoelectric counter of saltating sand particles

D.V. Buntov1, R.A. Gushchin1,2, O.I. Datsenko1,2
1A.M. Obukhov Institute of Atmospheric Physics Russian Academy of Sciences, Pyzhevsky per., 3, 119017, Moscow, Russia
2Moscow Technological University, Prospekt Vernadskogo, 78, Moskva, 119454
Keywords: ветропесчаный поток, сальтация, концентрация сальтирующих песчинок, распределение песчинок по размерам, четырехканальный фотоэлектрический счетчик, аппроксимация функции распределения, логнормальное распределение, sand wind flux, saltation, saltating sand particle concentration, particle size distribution, four-channel photoelectric counter, size distribution approximation, lognormal distribution

Abstract >>
A four-channel photoelectric counter has been worked out and manufactured for the measurements of saltating sand concentration fluctuations and size distribution function of particles with diameters > 30 mm over desertified areas. The measurement results are given. It is shown that the vertical profile of the saltating sand concentration does not change on average in the altitude range from 3 to 7 cm over a desertified area in the neighbourhood of Volga. The distribution function of saltating sand particles over the desertified area is approximated with satisfactory precision by the lognormal distribution near the distribution maximum. Noticeable distinctions between above mentioned distributions for large and small sand particles are observed.



12.
Dispersion of droplets in the nozzle spray cone

V.A. Arkhipov1,2, N.N. Zolotorev1, S.A. Basalaev1, S.S. Bondarchuk2,3
1National Research Tomsk State University, 36, Lenin Avenue, Tomsk, 634050, Russia
2Institute for Problems of Chemical and Energetic Technologies of the Siberian Branch of the RAS, 659332, Biysk, 1, Sotsialisticheskaja str., IPCET SB RAS
3Tomsk State Pedagogical University, 634041, Tomsk, 60, Kievskaya str., Russia
Keywords: жидко-капельный аэрозоль, центробежная форсунка, факел распыла, индикатриса рассеяния, метод малых углов, гамма-распределение, экспериментальное исследование, liquid-drop aerosols, centrifugal nozzle, spray cone, scattering phase function, small-angles method, gamma-distribution, experimental study

Abstract >>
The technique and results of an experimental study of the disperse composition of a liquid-drop aerosol in the nozzle spray cone are presented. To determine the particle size in the spray cone using the method of measuring the small-angle scattering phase function a new experimental setup was used. The parametric analysis is carried out. The criterion relations for the maximum diameter of the particles in the spray of the centrifugal nozzle are presented. It is shown that the particle size spectrum in the spray cone corresponds to the gamma distribution.



13.
Estimation of the influence of meteorological and orographic conditions on the aerosol contamination of snow cover in south of Tomsk region

B.D. Belan1, V.S. Buchelnikov2, V.F. Lysova3, D.V. Simonenkov1, A.V. Talovskaja2, M.P. Tentyukov1,3, E.G. Yazikov2
1V.E. Zuev Institute of Atmospheric Optics of Siberian Branch of the Russian Academy of Science, 1, Academician Zuev square, Tomsk, 634021, Russia
2National Research Tomsk Polytechnic University, 30, Lenin Avenue, Tomsk, 634050, Russia
3Pitirim Sorokin Syktyvkar state University, 12, Petrozavodskaya, 167005, Russia
Keywords: ветровой режим, орографические условия, расчлененность рельефа, аэрозольное загрязнение снега, типоморфные микроэлементы, угольные предприятия, wind regime, orographic conditions, relief subdivision, aerosol snow contamination, typomorphic microelements, coal enterprises

Abstract >>
Dynamics of layer-by-layer variability of aerosol contamination of snow cover in circulating conditions in winter period at the experimental site of the "Fonovaja" observatory (Institute of Atmospheric Optics of SB RAS) in the Tom-Ob interfluve 60 km west of Tomsk is analyzed. The chemical composition of the snow cover at the point of observation is characterized. It is established that in the elemental composition of the aerosol substance accumulated in the snow layer, a typomorphic association of indicator elements associated with coal mining is steadily manifested. The conclusion about the seasonal impact on the aerosol field of the "Fonovaja" observatory of enterprises of the coal-mining complex located to the south of the investigated territory is geochemically substantiated. It has been shown that the detection of remote sources of aerosol contamination of the snow cover is expedient to base on the morphometric analysis of the terrain and a retrospective estimate of the temporal variability of the indicators reflecting the effect of meteorological factors (dispersion ratio of surface aerosol, wind regime, snowfall intensity) and in context of the analysis of the features of the layered distribution of indicator groups of typomorphic elements, characterizing specific types of enterprises, in the snow layer.



14.
Experimental study of the evolution of fine particles by methods of aerosol cloud generation

M.Y. Stepkina, O.B. Kudryashova, A.A. Antonnikova, E.V. Muravlev
Institute for Problems of Chemical and Energetic Technologies of the Siberian Branch of the RAS, 659332, Biysk, 1, Sotsialisticheskaja str., IPCET SB RAS
Keywords: аэрозоль, распыление, генерация, ультразвуковое воздействие, осаждение, средний объемно-поверхностный диаметр, метод малоуглового рассеяния, aerosol, dispersion, generation, ultrasonic exposure, precipitation, surface-volume mean diameter, small-angle scattering method

Abstract >>
Different ways of dispersion of solid-phase particles are considered: pulse, electrostatic, and pneumatic. The model experiment on sedimentation of fine airborne particles of polymeric substance kollidon is made. A change in the concentration of the studied aerosol particles at ultrasonic sedimentation is analysed. The pilot study has shown that electrostatic generation of aerosol considerably increases the speed of sedimentation of particles with application of ultrasound.