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Combustion, Explosion and Shock Waves

2023 year, number 1

Kinetic Mechanism of Ignition of Propane-Butane Mixtures at Low and High Temperatures: Development and Application

V. A. Savel'eva, A. M. Savel'ev, N. S. Titova
Baranov Central Institute of Aviation Motors, Moscow, Russia
Keywords: alternative fuel, ignition, oxidation, kinetic mechanism, simulation

Abstract

A kinetic model for the ignition and combustion of mixtures of propane and n-butane in the air has been developed. The model contains 348 reactions involving 72 species and includes both a high and low-temperature mechanism of propane and n-butane oxidation. The kinetic model was tested against experimental data on the ignition delay time and laminar flame speed. The model provides a good fit to experimental data on propane ignition and the laminar flame speed in propane-air mixtures, ignition of n-butane under different initial conditions (T0 = 670 ÷ 1 550 K, ρ0 = 1 ÷ 30 atm, φ = 0.3 ÷ 2.0), laminar flame speed in mixtures of n-butane with air at T0 = 298 K, ρ0 = 1 atm, and various stoichiometric ratios φ= 0.67 ÷ 1.5), as well as on the ignition of stoichiometric C3H8/C4H10/N2/Ar mixtures with different relations C3H8/C4H10 at T 0 = 710 ÷ 910 K and ρ0 = 17.8 atm. The developed kinetic mechanism was used to perform a demonstration numerical simulation of combustion of propane-butane fuel in a homogeneous combustion chamber