Gas Chromatographic Analysis of Methane Pyrolysis Products during Laser Evaporation of CrOx/Al2O3 Nanoparticles in a Methane-Argon Environment
A. N. Pyryaev1,2, Vl. N. Snytnikov1
1Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Novosibirsk State University, Novosibirsk, Russia
Keywords: nanoparticles, methane, pyrolysis, gas chromatography, laser evaporation
Abstract
This paper presents the results of a chromatographic analysis of gaseous products formed during the laser synthesis of catalytic Cr/Al2O3 nanoparticles in a methane-argon environment. The main difficulties of such studies are noted. Methods for solving this problem and ways to optimize the methane pyrolysis accompanying the laser synthesis of nanoparticles are proposed. The fundamental possibility of simultaneous synthesis of catalytic nanoparticles and their use for methane pyrolysis is demonstrated. The main products of pyrolysis in this process are hydrogen and amorphous carbon. The maximum hydrogen yield is 4% (vol.). It is shown how the process can be optimized to increase the yield of hydrogen and expand the range of reaction products for unsaturated hydrocarbons.
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