D. A. Tropin, A. V. Fedorov
Khristianovich Institute of Theoretical and Applied Mechanics, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
Keywords: смесь водород/силан/воздух, время задержки воспламенения, детальная химическая кинетика, математическое моделирование, Hydrogen-silane-air mixture, ignition delay time, detailed chemical kinetics, mathematical modeling
Based on the previously developed model of detailed kinetics, the ignition delay time of hydrogen-silane/air two-fuel mixtures is calculated. The effect of the silane concentration and the temperature of the mixture on the ignition delay time is determined. It is shown that addition of a small (within 20%) amount of silane to the hydrogen-air mixture in the temperature range from 1200 to 2500 К leads to significant reduction of the ignition delay time of the mixture, whereas there is only a minor decrease in mixtures with silane concentrations greater than 20%.
A. A. Vasil'ev1,2, A. V. Pinaev1, A. A. Trubitsyn1, A. Yu. Grachev1, A. V. Trotsyuk1, P. A. Fomin1, A. V. Trilis1 1Lavrentyev Institute of Hydrodynamics, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia 2Novosibirsk State University, Novosibirsk, 630090 Russia
Keywords: метан, угольная пыль, горение, детонация, пределы, переход горения в детонацию, шахтные взрывы, подавление взрывов, methane, coal dust, combustion, detonation, limits, deflagration-to-detonation transition, coal mine explosions, explosion suppression
Possible scenarios of ignition and explosion development in coal mines are discussed. A principal possibility of complete quenching of detonation and combustion with the use of a sheet consisting of inert particles is experimentally demonstrated. As the detonation quenching process is rather complicated, it is recommended to focus the attention at the initial stage of ignition of the methane-air mixture, when it is possible to ensure effective quenching of the ignition site by using methods of advanced automatic monitoring and control with clear satisfaction of space and time requirements.
I. V. BELENKAYA1, M. P. POPOV1, I. A. STARKOV1, O. A. SAVINSKAYA1, S. F. BYCHKOV1, and A. P. NEMUDRY1,2 1Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences, Ul. Kutateladze 18, Novosibirsk 630128 (Russia) 2Novosibirsk State University, Ul. Pirogova 2, Novosibirsk 630090 (Russia) E-mail: nemudry@solid.nsc.ru
Keywords: nonstoichiometric perovskites, oxygen permeable membranes, oxygen transport mechanism
Pages: 357–366
A strategy of targeted regulating functional properties of perovskite-like oxides with mixed oxygen-electronic conductivity (MOEC) using ferroelectric high-valent dopants (Nb, Ta, Mo, and W) is presented. New research methods of the oxygen stoichiometry and oxygen exchange kinetics in MOEC oxides were proposed. Research results of oxygen permeability of membranes based on the elaborated materials were discussed.
N. V. KOSOVA and E. T. DEVYATKINA
Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences, Ul. Kutateladze 18, Novosibirsk 630128 (Russia) E-mail: kosova@solid.nsc.ru
Keywords: lithium-ion rechargeable batteries, cathode materials, Li3V2(PO4)3, LiVPO4F, mechanical activation, crystal structure, cycling
Pages: 367–374
By the mechanochemically stimulated solid-phase synthesis, new nanostructured cathode materials based on vanadium were obtained: Li3V2(PO4)3, LiVPO4F and their composites LiVPO4F/Li3V2(PO4)3. The crystal structure and electrochemical properties of the synthesized compounds were studied by means of XPA with refinement according to Rietveld and chronopotentiometry. It was demonstrated that Li3V2(PO4)3 is stably cycling within the voltage range 3.0–4.3 V, in particular at high current density. Improvement of the cathode characteristics of LiVPO 4F is promoted by obtaining composite materials LiVPO4F/Li3V2(PO4) 3 with nanodomain structure. The possibility to use LiVPO4F in symmetric cells with the voltage of 2.4 V is demonstrated.
M. V. CHAIKINA1, N. V. BULINA1, I. YU. PROSANOV1, A. V. ISHCHENKO2, and S. G. STOLYAROVA3 1Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch of the Russian Academy of Sciences, Ul. Kutateladze 18, Novosibirsk 630128 (Russia) E-mail: chaikinam@solid.nsc.ru 2Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Pr. Akademika Lavrentyeva 5, Novosibirsk 630090 (Russia) 3Novosibirsk State University, Ul. Pirogova 2, Novosibirsk 630090 (Russia)
Keywords: mechanochemical synthesis, zirconium-substituted apatite
Pages: 375–384
The possibility to obtain a zirconium-substituted apatite by the method of mechanochemical synthesis was studied. It was established that zirconium oxide or zirconium hydroxide could be used as the source of zirconium for this synthesis. It is preferable to use zirconium hydroxide, as in the process of the mechanochemical synthesis, the major part of the oxide remains in the initial state. In case of the hydroxide, the intermediate phase of the double oxide contributing to further synthesis is formed.
V. A. POLUBOYAROV1, Z. A. KOROTAEVA1, I. A. PAULI2, A. A. ZHDANOK1, and G. E. SELYUTIN3 1Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch of the Russian Academy of Sciences, Ul. Kutateladze 18, Novosibirsk 630128 (Russia) E-mail: sanych@solid.nsc.ru 2Siberian State University of Communication Lines, Ul. Dusi Kovalchuk 191, Novosibirsk 630049 (Russia) 3Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences, Ul. K. Marksa 42, Krasnoyarsk 660049 (Russia)
Keywords: polymeric nanocomposites, nanodispersed ceramic powders, modifying, strengthening, near-surface phase, X-ray phase analysis, crystallinity
Pages: 385–392
Research results of the effect of nanodispersed ceramic powders on properties of nanocomposites based on high pressure polyethylene are given. It has been shown that the addition of the nanodispersed modifiers SiC, TiO2 leads to grinding up polyethylene grains up to the sizes of less than 0.1 μm. Herewith, an increase of the density and fastness to rubbing of polyethylene is observed, as well as the decrease in gas permeability (in 1.5 times) and water vapour permeability (in 1.7 times).
N. Z. LYAKHOV, YU. M. YUKHIN, R. K. TUKHTAEV, K. V. MISHCHENKO, A. I. TITKOV, and O. A. LOGUTENKO
Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences, Ul. Kutateladze 18, Novosibirsk 630128 (Russia) E-mail: lyakhov@solid.nsc.ru
Keywords: nanopowders of silver, copper, nickel and bismuth, these metals carboxylates, ethylene glycol, benzyl alcohol, reduction
Pages: 393–400
The products formed at the reduction of silver, copper, nickel and bismuth carboxylates were investigated by methods of chemical, X-ray phase, differential thermogravimetric analyses and electronic microscopy at heating in the environment of high-boiling organic liquid. It was shown that powders of silver, copper, nickel, bismuth and of alloys of these metals of the submicron size could be obtained by the way of reduction of these metals carboxylates by ethylene glycol and benzyl alcohol. Structural morphological features of powders obtained, as well as the influence on these parameters of the length of the methylene chain of the starting carboxylate, its morphology and the process of doping by cations of other metals were investigated.
A. G. BELOBABA, A. G. ZELINSKIY, A. A. GUSEV, and A. I. MASLIY
Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences, Ul. Kutateladze 18, Novosibirsk 630128 (Russia) E-mail: belobaba@ngs.ru
Keywords: indium-tin oxides, ITO, cathode reduction, anodic dissolution, magnetron targets
Pages: 401–406
The electrochemical activity of mixed indium-tin oxides (ITO) at the cathode and anode treatment in various solvents was studied. It was established that in case of the anodic polarization at potentials that are more negative than the potential prior to the beginning of hydrogen evolution in appropriate solutions of ITO were reduced to the metals In and Sn followed by the formation of intermetallides. It was shown at the anodic treatment the nature of the acid and current density had a big impact on the rate of the anodic dissolution of ITO. The dissolution rate in HCl is lower than in H2SO4 and significantly reduced with the increase of the acid concentration due to the acceleration of the side reaction of the evolution of Cl2. The electrochemical activity of ITO at the cathode and anodic treatment in solutions allows using electrolysis for the disposal of used magnetron targets or ITO scraps.
T. P. ALEKSANDROVA1, A. A. VAIS1, A. I. MASLIY1, V. A. BURMISTROV2, A. A. GUSEV1, and S. K. BAGAVIEVA3
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Keywords: synthetic fibres, silver-containing coatings, antimicrobial properties
Pages: 407–411
Chemical and electrochemical methods of the application of nanolayers of silver metal and its poorly soluble compounds (silver chloride and oxide) on the surface of polymeric fibers were considered. The morphology and phase composition of coatings were studied. A comparative evaluation of the antimicrobial activity of the obtained materials on various bacterial cultures was presented. It was shown that the antimicrobial activity of coatings significantly increased with the rise of their solubility. Due to the developed surface and a high porosity, synthetic fibres with such coatings are particularly promising for the application as antimicrobial filters in the purification systems and air conditioning, as well as the water treatment system.
V. P. ISUPOV, S. S. SHATSKAYA, and I. A. BORODULINA
Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences, Ul. Kutateladze 18, Novosibirsk 630128 (Russia) E-mail: isupov@solid.nsc.ru
Keywords: mineralized lakes, Mongolia, Altai Territory, Gorny Altai, chemical composition, uranium, microcomponent composition, sorption extraction of uranium
Pages: 413–420
Data on the content of uranium and other components in mineralized lakes of Western Mongolia and the adjacent territory of the Russian Federation were generalized. It was revealed that soda lakes of the studied regions were characterized by an increased content of uranium. The assessment of reserves of uranium and other micro- (Li, Br, B, As, etc.) and macroelements in lake waters was performed. Geochemical sources of uranium accumulation in lake systems, and forms of its deposition in water and bottom sediments of lakes were analyzed. Possible variants of the way of extracting uranium and other precious components from lake waters were considered.