V.M. Solovyev1, A.S. Sal’nikov2, V.S. Seleznev3, T.V. Kashubina4, N.A. Galeva1, A.E. Shenmaier1 1Altai-Sayan Branch of the Geophysical Survey of the Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia 2Trofimuk Institute of Petroleum Geology and Geophysics, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia 3Seismological Branch of the Geophysical Survey of the Siberian Branch of the Russian Academy of Sciences, Novosibirsk, pr. Akademika Koptyuga 3, Russia 4A.P. Karpinsky Russian Geological Research Institute, St. Petersburg, Russia
Keywords: Deep seismic sounding profile, longitudinal wave, transverse wave, P-wave velocity, S-wave velocity, deep seismic section, Earth’s crust, mineragenic zone
Results of deep seismic studies based on P- and S-wave data on a 500-km Sikhote-Alin fragment of the 8-DV reference geophysical profile are presented. Deep seismic sections of the upper crust (to depths of 15-20 km) with distributed longitudinal and transverse wave velocities are constructed. The P-wave velocity over most of the Middle Amur Basin and the East Sikhote-Alin volcanoplutonic belt varies from 4-5 km/s in the uppermost section to 5.8-6.3 km/s at depths of 7-15 km. The Sikhote-Alin orogenic belt in the section along the profile is represented by an anticlinal structure with high-velocity (up to 5.5-5.8 km/s) rocks uplifted in the center; at great depths of 10-20 km within its limits, the P-wave velocities reach 6.1-6.3 km/s. In the top of the section, the S-wave velocities within the profile as a whole are 2.7-2.9 km/s. Lower values (2.6-2.8 km/s) are observed in the center and east of the Middle Amur Depression and the eastern section of the East Sikhote-Alin volcanoplutonic belt. Higher velocities up to 3.35 km/s are observed in the central Sikhote-Alin orogenic complex. At depths of 5-15 km within the section, the S-wave velocities increase up to 3.4-3.65 km/s. The heterogeneous structure of the top of the Earth’s crust to depths of 15-20 km was identified using the P- and S-wave velocities, their ratio, and Poisson’s ratio. The profile section was used to analyze a relationship between the identified anomalies and the location of large mineragenic zones in Russian Manchuria. The correlations established earlier on the 2-DV, 3-DV, 1-SB, and East Stanovoy fragment of the 8-DV profile are confirmed using the confinement of many ore deposits to zones of lower P- and S-wave velocity ratios and Poisson’s ratio in the top of the Earth’s crust. We also substantiated the relationship between the identified surface seismic anomalies and deep (at depths of 5-20 km) roots (intermediate magmatic foci), which can be considered as ore-supplying.
N.A. Lykov1,2, Yu.V. Rostovtseva3, I.G. Zakiryanov4, A.V. Timokhin4, A.V. Dronov1, T.V. Gonta4, O.V. Postnikova1 1Geological Institute, Russian Academy of Sciences, Moscow, Russia 2Gubkin Russian State University of Oil and Gas, Moscow, Russia 3Geophysical Center, Russian Academy of Sciences, Moscow, Russia 4Trofimuk Institute of Petroleum Geology and Geophysics, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
Keywords: Calcareous cyanobacteria, Ortonella, Garwoodia, Hedstroemia, bioherm, biostrome, bivalve banks, uppermost Middle Ordovician, cyanotoxins, Siberian Platform
Remains of calcareous cyanobacteria of the genera Garwoodia Wood, 1941, Ortonella Garwood, 1914 and Hedstroemia Rothpletz, 1913 (Garwoodiaceae family) were first identified in the late Darriwilian deposits of the Moyero River section (Eastern Siberia). Ortonella and Garwoodia were previously found on the Siberian Platform only in Silurian deposits, making this the earliest discovery of representatives of these genera in the region. Ortonella and Garwoodia dominate, whereas Hedstroemia occupy a subordinate position in stromatoporoid-cyanobacterial bioherms. Only Ortonella was found in biostromes and shell interlayers of the bivalve banks. The sediments in question accumulated in the shallow-water lagoonal environment. The latter determined the failure of skeletal metazoan organisms to become the main frame builders of biostromes and bioherms, despite the global increase in biodiversity during the Great Ordovician Biodiversification Event (GOBE). Their role was taken over by cyanobacterial communities, which proved more resistant to such environmental conditions. The increase in phosphorus content in bottom sediments apparently triggered the development of cyanobacteria; which probably caused a local paleoecological crisis of the benthic fauna in this part of the paleobasin. The latter is confirmed by the depleted ostracod assemblage in the Moyero River section (in contrast to coeval deposits of the Lena, Podkamennaya Tunguska, and Kulyumbe river sections). The decline in biodiversity of benthic fauna and, particularly, of skeletal metazoan frame builders during cyanobacterial “blooms” may be explained by the impact of cyanotoxins, which are destructive to marine life. The data obtained demonstrate that even in the age of global biotic expansion of the Ordovician period, local conditions could limit the contribution of skeletal metazoans to reef construction, maintaining the dominance of microbial communities.
V.V. Marusin1,2 1Trofimuk Institute of Petroleum Geology and Geophysics, Siberian Branch of Russian Academy of Sciences, Novosibirsk, Russia 2Novosibirsk State University, Novosibirsk, Russia
Keywords: Vendian, Cambrian, General Stratigraphic Scale of Russia, International Chronostratigraphic Chart, small shelly fossils, trace fossils, chemostratigraphy, Siberian Platform
A recent revision of the volume and the age of the Nemakit-Daldynian Stage of the Upper Vendian articulated its comprehensive (bio- and chemostratigraphic) characteristic. This stage includes strata ranging from the first appearance of unequivocal anabaritids (approximately 539 Ma) to the base of the Nochoroicyathus sunnaginicus Assemblage Zone of the Lower Cambrian Tommotian Stage (530 Ma). In addition to the characteristic assemblages of small shelly fossils (SSF), this stratigraphic interval is defined by specific changes in the trace fossil assembalges and by variations of carbon isotope composition in carbonates. Using the established criteria, this study evaluates the completeness of the Nemakit-Daldynian Stage in its type locality (western Anabar Uplift) and in other sections of the Siberian Platform (eastern Anabar Uplift, Olenek Uplift, Kharaulakh Uplift, Uchur-Maya Region, Patom Basin, Baikal area, Irkutsk Cis-Sayans Uplift, Biryusa Cis-Sayans Uplift, southern Yenisei Ridge, northern Yenisei Ridge, Turukhansk Uplift, Igarka Uplift, and inner regions of the Platform).
N.I. Maksimenko, T.G. Shumilova
Institute of Geology of Komi Science Centre of the Ural Branch of the Russian Academy of Sciences, Syktyvkar, Russia
Keywords: Suevite, impactite, impact facies, shock metamorphism, impactite genesis, Kara astrobleme
The impact facies are subdivided into coptogenic (primarily deposited) and coptomict (redeposited) units. The redeposited impact facies have been poorly studied. In this work, the deposits of the coptomict facies are characterized in detail for the first time by the example of the Kara astrobleme. The structures and textures of impactites are examined at the macrolevel, and the structural and compositional specifics of the components (lithoclasts, vitroclasts, and matrix) of lapilli and agglomerate suevites of the Sayakha River area have been described at the microlevel. The reconstruction of the past events has shown that the clastic impactites of the northwestern rim of the Kara astrobleme formed under conditions of landslide from the crater lip at the stage of the early modification of the astrobleme. The results obtained can be used to construct a model for the formation of the Kara impact structure and to improve the unified model for the formation of clastic impactites of the coptomict facies in a large meteorite crater.
P.A. Solotchin1, E.P. Solotchina1, A.E. Maltsev1, G.A. Leonova1, A.N. Zhdanova1, S.K. Krivonogov1,2, I.V. Danilenko1 1V.S. Sobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia 2Korkyt Ata Kyzylorda University, Kyzylorda, Kazakhstan
Keywords: Hypersaline lake, Holocene, bottom sediment, mineralogy, X-ray diffractometry, carbonate, crystal chemistry, paleoclimate, Western Siberia
We report the results of lithological and mineralogical studies of Holocene bottom sediments from the hypersaline Lake Bolshoe Yarovoe (salinity 150 g/L), located on the territory of the Kulunda steppe (south of Western Siberia). Research methods: X-ray diffractometry (XRD), IR spectroscopy, laser grain-size analysis, elemental analysis, and radiocarbon dating. The thickness of the uncovered sediments is 483 cm. Terrigenous minerals throughout the section are represented by quartz, plagioclase, and layered silicates (mica, chlorite, smectite, and kaolinite). The variable amounts of omnipresent authigenic minerals include halite, gypsum, carbonates, and traces of pyrite. We identified Mg-calcites with different Mg contents and aragonite using the mathematical modeling of X-ray diffraction patterns in the assemblage of carbonate minerals. The mineralogical and crystallochemical studies of sediments supplemented by the results of other analyses have provided information about the evolution of the climate of the Kulunda steppe in the Middle to Late Holocene. The comparatively arid regional climate of the Middle Holocene became more humid in the first half of the Subatlantic, but aridization signs reappeared in the section about 600 years ago (Little Ice Age).
Maxwell’s equations and the equations of two-velocity hydrodynamics of saturated porous media are consistently combined in the absence of local thermodynamic equilibrium. Equations describing relaxation of dielectric polarization vector are inferred. The law of dielectric permittivity dispersion is established in the presence of two interacting relaxation processes: relaxation of the difference in hydrodynamic velocities and relaxation of dielectric polarization. Relationship between kinetic coefficients and complex dielectric permittivity is shown, particularly relationship with hydrodynamic permeability of porous medium. A method for determining the hydrodynamic permeability of a porous medium, which does not take into account the relaxation time distribution function, based on knowledge of the dielectric spectrum was developed. Medium’s dielectric response to external inductive effect is examined for wells in saturated porous media.
G.I. Gromilin1, V.P. Kosykh1, Yu.N. Siniavskii1,2, N.S. Yakovenko1 1Institute of Automation and Electrometry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia 2Federal Research Center for Information and Computational Technologies, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
Keywords: "point" object, spatially nonstationary background, neural network, detection
The efficiency of using a neural network for detecting "point" objects whose shape is determined by the characteristics of the recording optical-electronic channel in images with a spatially nonstationary background is studied. The training data sets take into account the diversity of background situations and the variability of the shape of the signal from objects due to their movement. The results of detecting objects of different brightness and colors on real background images obtained during observation of the Earth's surface from a geostationary orbit are presented.
M. Yu. Reushev1,2, D.S. Makarov1, D.V. Kharlamov1, V.G. Podoprigora3,2, K.V. Krasnoschekov1 1Federal Research Center “Krasnoyarsk Scientific Center of the Siberian Branch of the Russian Academy of Sciences", Krasnoyarsk, Russia 2Siberian Federal University, Krasnoyarsk, Russia 3L.V. Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russia
Keywords: GNSS reflectometry method, ice surfaces of water bodies, fast Fourier transform technique, navigation satellite signals, L1 range
Reflectometric measurements of the ice surface conditions of reservoirs in the Krasnoyarsk Krai and the Republic of Khakasia are conducted using radio signals from navigation satellites emitting in the L1 band. During processing of the resultant reflectograms, mathematical processing of the amplitude-time dependencies is applied using the fast Fourier transform method, allowing for the experimental determination of ice cover thicknesses with various macrophysical characteristics.
S. I. Vyatkin, B. S. Dolgovesov
Institute of Automation and Electrometry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
Keywords: functionally defined surfaces, perturbation functions, Fourier transform, bidirectional reflectance distribution function, specular reflection, diffuse reflection, geometric optics, physical optics, diffraction, interference
Functionally defined surfaces with a complex microstructure are offered for realistic scenes. A model based on wave optics is described for visualizing surfaces with microscale roughness, which increase the realism of objects under various observation and lighting conditions because of diffraction and mutual interference. The model includes modeling of light transfer and surface, which serve as its initial data. The diffraction effects taking into account the surface roughness are shown. An approximation of spatial coherence using a Gaussian filter is considered; as a result, it is possible to visualize not only the glare, but also the diffraction of higher orders.
I. A. KRUPNOVA, G. T. SUKHANOV
Institute for the Problems of Chemical and Energetic Technologies, Siberian Branch of the Russian Academy of Science, Biysk, Russia
Keywords: 3-нитро-1,2,4-триазол-5-он, селективность, нуклеофильное замещение, нитрация, 3-nitro-1,2,4-triazole-5-one, selectivity, nucleophilic substitution, nitration
Pages: 402-407
The chemistry of heterocyclic compounds has become one of the most dynamically developing fields of organic chemistry in recent decades. The role the heterocyclic compounds play in different areas of science and technology (chemistry, medicine, biology, electronics, etc.) can hardly be overestimated. In this regard, the development of new synthetic methods for functional derivatives of various heterocyclic compounds still holds relevance. Pharmaceuticals such as Trazodone, Nefazodone, Aprepitant, Itraconasole and others, which comprise the 1,2,4-triazol-5-one moiety, are widely used in modern medicine and pharmacy. The synthesis and characterization of the compounds of this series are of theoretical and practical interest. The design of novel drugs is based both on the directed synthesis of new drugs and on the screening of bioactive compounds derived by modifying the known drug molecules. Here we report two methods that give access to 3-nitro-1,2,4-triazol-5-one (NTO) alkyl derivatives, which is not possible via other common approaches. The success of our methods is due to the use of preparatively obtainable starting substrates and to the positional selectivity of all the reactions along a specified nitrogen atom. The strategy devised herein contributes to the progress in the theory of reactivity of ambident heterocycles and allows for selective synthesis of never-before-seen 1-substituted derivatives of NTO. The virtual screening of N-functionalized derivatives of 3-nitro-1,2,4-triazole and 3-nitro-1,2,4-triazole-5-one, which were obtained by the nucleophilic substitution of the nitro group, saponification and nitration, has shown their high biological activity in the most demanded areas of medicine - disease treatment, prevention and rehabilitation: cardiovascular diseases; diseases of the nervous system (neuromediators, neuroprotectors); anticancer drugs (cancer growth blockers). Therefore, such compounds arouse elevated interest among researchers in Russia and overseas.