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Thermophysics and Aeromechanics

2025 year, number 2

Thermal conductivity and thermal diffusivity of magnesium-lithium alloys

A.Sh. Agazhanov1, R.N. Abdullaev1, D.A. Samoshkin1, V.A. Nepomnyashchikh1,2
1Kutateladze Institute of Thermophysics, SB RAS, Novosibirsk, Russia
2Novosibirsk State University, Novosibirsk, Russia
Keywords: magnesium-lithium alloys, ultra-light materials, thermal conductivity, thermal diffusivity, laser flash method

Abstract

The thermal diffusivity (α) of solid magnesium-lithium alloys with lithium contents XLi = 5, 10, 17, 21, and 25 at. % was measured using a laser flash method in the temperature range of 300 - 680 K. Based on the experimental results, the thermal conductivity (λ) of alloys was calculated and compared with the literature values for λ of other compositions. The estimated uncertainties of the obtained data were 3.0 - 3.4 % for λ and 2.0 - 2.4 % for α. It is shown that the addition of lithium to magnesium reduces significantly its thermal conductivity, with a more pronounced decrease in λ observed as the Li concentration approaches XLi = 32 at. %. Anomalous features in the form of bends in the temperature dependences λ(T) and α(T) were identified for the Mg95Li5 and Mg75Li25 alloys within the temperature range of 310 - 330 K, similar to the behavior reported for the Mg70Li30 alloy. Using the calculated data and literature sources, the concentration dependences of thermal conductivity for the Mg-Li system were plotted over the composition range XLi = 0 - 32 at. %.