This article continues the theme of repatriation represented in the last year's issue (2) of "The Humanities in Siberia" and throws light upon one of the stages of intergovernmental migration between the USSR and China. The work is based on the material of funds of the Council of Ministers of the USSR, Ministry of Foreign Affairs and the Department of Repatriation. The author examines the activities of the special Department deputed by the Soviet Government to solve the problem of repatriation of the Soviet population from countries of Europe and Asia, according to the Treaty concluded after the end of the World War II. The number of the Soviet people transferred from China and their placing on the territory of Ural, Siberia and the Far East are determined.
VALERY M. DEMBITSKY1 and GENRICH A. TOLSTIKOV2 1Department of Pharmaceutical Chemistry and Natural Products, School of Pharmacy, The Hebrew University of Jerusalem, P. O. Box 12065, Jerusalem 91120 (Israel) E-mail: dvalery@cc.huji.ac.il 2Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Pr. Akademika Lavrentyeva 9, Novosibirsk 630090 (Russia) E-mail: gtolstik@nioch.nsc.ru
Pages: 557-565
The structures of hundred halogenated metabolites of phenolic nature generated by lichens and fungi are considered. The groups of depsides, depsidones, fungoid metabolites are marked out. The problems related to biological activity are discussed.
VALERY M. DEMBITSKY1 and GENRICH A. TOLSTIKOV2 1Department of Pharmaceutical Chemistry and Natural Products, School of Pharmacy, The Hebrew University of Jerusalem, P. O. Box 12065, Jerusalem 91120 (Israel) E-mail:dvalery@cc.huji.ac.il 2Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Pr. Akademika Lavrentyeva 9, Novosibirsk 630090 (Russia) E-mail: gtolstik@nioch.nsc.ru
Pages: 567-575
Mononuclear halogenated simple phenol compounds and their derivatives formed from mono- and polyhydroxybenzenes are represented in nature by metabolites of insects, fungi, plants and microorganisms living on land and in water. The structures of a hundred compounds of phenol, quinones and cyclitol types, their metabolism and data on their biological activity are considered in the review.
NIKOLAY M. BAZHIN
Institute of Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, Ul. Institutskaya 3, Novosibirsk 630090 (Russia) E-mail: bazhin@ns.kinetics.nsc.ru
Pages: 577-580
OLGA A. GOLOVANOVA1, POLINA A. PYATANOVA1, NADEZHDA A. PALCHIK2, VALENTINA N. STOLPOVSKAYA2, TAMARA N. GRIGORYEVA2, ALEXANDER I. NIZOVSKIY3 and SERGEI S. SHKURATOV4 1Omsk State University, Pr. Mira 55a, Omsk 644077 (Russia) E-mail: PAKach@orgchem.univer.omsk.ru 2Trofimuk United Institute of Geology, Geophysics and Mineralogy, Siberian Branch of the Russian academy of Sciences, Pr. Akademika Koptyuga 3, Novosibirsk 630090 (Russia) E-mail: nadezhda@uiggm.nsc.ru 3Boreskov Institute of Catalysis, Omsk Division, Siberian Branch of the Russian Academy of Sciences, Ul. Neftezavodskaya 54, Omsk 644040 (Russia) 4Region Clinic, Ul. Nemirovicha-Danchenko 130, Novosibirsk 630015 (Russia)
Pages: 581-587
Investigation of endemic features of urolithiasis taking into account local factors, both natural and technology-related ones, allows one to obtain additional information about one of the reasons of this disease. Mineral composition and distribution of urinary calculi in patients from Novosibirsk and Omsk Regions are investigated. A common feature of urolithiasis in the regions under comparison is noticeable predominance of oxalate urinary calculi. However, at the conservation of the general trend of distribution with respect to the prevailing component, patients from Novosibirsk Region exhibit an increase in phosphate and decrease in urate urolithiasis. Noticeable differences in paragenesis of minerals comprising multicomponent urinary calculi and in the composition of single-component concretions are observed. In the Novosibirsk samples, single-mineral concretions are more frequently composed of whwellite, while in the Omsk samples it is anhydrous uric acid. Comparative analysis of the mineral composition and distribution of urinary calculi in other regions according to literature data was carried out.
PETER N. KUZNETSOV1, LYUDMILA I. KUZNETSOVA1, ANATOLIY M. ZHYZHAEV1, GENNADIY L. PASHKOV1and VLADIMIR V. BOLDYREV2,3 1Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences, Ul. K. Marxa 42, Krasnoyarsk 660049 (Russia) 2Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch of the Russian Academy of Sciences, Ul. Kutateladze 18, Novosibirsk 630128 (Russia) 3Novosibirsk State University, Ul. Pirogova 2, Novosibirsk 630090 (Russia) E-mail: kuzpn@krsk.info
Pages: 611-619
The effect of mechanical activation of amorphous zirconium hydroxide in centrifugal planetary mill on the formation of crystalline zirconia in the presence of Fe3+ and Y3+ cation additives is investigated. It is established that the pulsed mechanical impact stimulates dehydration and crystallization of the nanosized metastable form of tetragonal zirconia in a mechanochemical apparatus at the room temperature. The solid-phase mechanochemical synthesis proceeds with a high rate through sequential and parallel routes with the intermediate formation of stable monoclinic modification of ZrO2. Introduction of additives favours the formation of the tetragonal form; in the presence of small amount of Y3+ cations, the process is completed within 2_5 min. The formation of metastable phase in the mechanochemical apparatus can occur due to the pulsed mode of powerful mechanical impact, resulting in the creation of thermodynamically and kinetically favourable conditions, and also due to small crystallite size (12_16 nm) as a result of efficient grinding.
NATALYA N. KULIKOVA, ALEXANDER N. SUTURIN, LYUDMILA F. PARADINA and SERGEY M. BOYKO
Limnological Institute, Siberian Branch of the Russian Academy of Sciences, Ul. Ulan-Batorskaya 3, Irkutsk 664033 (Russia) E-mail: kulikova@lin.irk.ru
Pages: 595-602
Analysis of the distribution of elements in biogeocenoses based on organomineral composts is performed. Introduction of composts of the wastes from plant and cardboard industry, heat-and-power engineering, cattle breeding did not cause accumulation of microelements in soils in concentrations exceeding the phytotoxicity level and maximum permissible values. Differences in microelemental composition of the experimental and reference plants were insignificant. Compost made of the wastes from industry can be used for reclamation of land disturbed by man's impact.
VICTOR N. MAKAROV, OLGA P. KORYTNAYA, ALLA S. LUGOVSKAYA, TATIANA N. VASILIEVA and DMITRIY V. MAKAROV
Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Sources, Kola Scientific Centre of the Russian Academy of Sciences, Ul. Fersmana 26a, Apatity 184200 (Russia) E-mail: makarovdv@chemy.kalasc.net.ru
Pages: 621-626
The effect of particle size of carbonate minerals (dolomite and calcite) on the kinetics of their interaction with water and ferrous sulphate solution is investigated. It is established that the efficiency of solution neutralization is to a noticeable extent determined by the particle size of the reagent. The application of calcite as a material for the construction of artificial geochemical barriers is preferential over dolomite. In the case when reagent consumption is much higher than the stoichiometric amount, or under lengthy interaction (for example, in filtering dams of artificial geochemical barriers) the particle size of the material has no substantial effect.
SOPHIA I. PECHENYUK, VASILIY V. SEMUSHIN and TATIANA G. KASHULINA
Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Sources, Kola Scientific Centre of the Russian Academy of Sciences, Ul. Fersmana 26a, Murmanskaya obl., Apatity 184209 (Russia) E-mail: pechenyuk@chemy.kolasc.net.ru
Pages: 627-633
The aging of freshly precipitated and immediately saturated with a sorbate (Cu(II), Ni(II), Cr(III), Pb(II) and Cd(II) cations) oxyhydroxides of Fe(III), Cr(III), Al(III), Zr(III) and Ti(IV) in 0.25 M solution of NaCl at room temperature is studied. It is established that the aging is accompanied by spontaneous acidification of the oxyhydroxide suspension and by partial desorption of the sorbate, which is to the highest extent exhibited with aluminium oxyhydroxide with Cd sorbed, and by the lowest extent with